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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 下载免费PDF全文
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
敦煌-格尔木铁路沿线地形复杂、起沙因素多变、沙源丰富,沙害问题日益严重。目前对其风沙活动规律还未有研究,不利于防沙工作的开展。为此,通过对自北向南的5个观测点(S1、S2、S3、S4、S5)风速和风向的观测、计算和分析,利用平均风速、起沙风况及输沙势对敦格铁路沿线的风动力环境特征进行研究。结果表明:S5、S4和S3的风况对铁路风沙灾害防治意义较大。S5年平均风速、起沙风频率和输沙势最大,春季风沙活动最为强烈,且风向单一、风力强劲,风沙运动方向基本与铁路垂直,沙粒易在铁路附近堆积。S4夏季风沙活动最为强烈;S3春季风沙活动最为强烈,且风向单一,S4和S3的风沙运动方向与铁路夹角小于90°,附近沙源广阔,铁路易受风沙侵蚀,阻碍交通运营。 相似文献
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阶地型古老滑坡体形成后,长期受各种营力影响,导致古老滑坡地貌形态破坏严重甚至消失。目前遥感技术和普通工程地质调绘很难发现这些滑坡的存在,给工程建设和后期运营造成较大安全隐患。为准确识别形态特征不明显的古老滑坡体,从阶地物质结构特征演变入手,找到阶地受剪切破坏产生的典型物质结构特征,将地层结构错断、卵砾石异常定向排列、摩擦镜面和泥包粒的眼球构造等作为滑坡准确识别依据。首先采用沿沟谷进行工程地质测绘的纵横交错追踪法确定滑坡体纵向范围和滑面形状,再结合地貌特征推测各级、块滑坡平面范围和分布,最后用点状勘探工程验证和校正推测结论。可将其总结为由"地貌异常、沿沟追踪、面上推断、点状校验"组成的阶地型滑坡识别方法,即物质结构异常推断法。结合线状工程勘察设计各阶段工作特点,提出线状工程前期工作中阶地型滑坡识别步骤,并在临渭高速公路工程建设项目中取得成功应用。 相似文献
5.
In order to investigate the effect of internal friction of umbilical cable on its vortex-induced vibration(VIV)responses, the experimental study on VIV of bond umbilical cable(BUC) and un-bond umbilical cable(UBUC) was carried out in an experimental tank. A current generator in the laboratory simulated the uniform current, and the current velocities were observed in real time by using a Doppler Velocimeter. In addition, different sizes of top tension were applied to the umbilical cable model. The VIV responses of the umbilical cable model were measured by using Fiber Bragg grating(FBG) strain sensors. The displacement responses of umbilical cable model were reconstructed based on the experimental strain data processed by modal superposition method. In this paper, the traveling wave characteristics, the spatial-temporal distribution characteristics of frequency and fatigue damage of the BUC and UBUC under VIV are studied. The experimental results show that there are obvious differences between BUC and UBUC in the response characteristics of VIV. The UBUC appears the traveling wave sooner than BUC, but its standing wave characteristics are more obvious than those of BUC at high velocities. Compared with BUC, the spatial-temporal distribution of UBUC frequencies appears wide-band distribution sooner, but has narrower bandwidth in the "lock-in" state. The level of fatigue damage of BUC was approximately the same as that of UBUC. 相似文献
6.
Kai Yao Dongliang An Na Li Chen Zhang Aizhao Zhou 《Marine Georesources & Geotechnology》2020,38(2):250-255
AbstractA series of direct shear tests were performed on cement-admixed silty clay to investigate the effect of cement content and nano-magnesia (MgO) on its shear strength properties. For each normal stress, shear strength increased with cement content. However, an obvious increment in shear strength was achieved when the cement content was adjusted from 13% to 17%. Both cohesion and friction angle of cemented soil increased with cement content, and exponential function was adopted to correlate both the factors with cement content. For cement content of 10% investigated in this study, the optimum nano-MgO content was 10‰, wherein the cohesion could reach the peak value. The microstructure of the mixture revealed that the structure of the mixture was compacted for the optimum nano-MgO content. However, micro-cracks were formed when the amount of nano-MgO exceeded its optimum content. 相似文献
7.
Li‐Yang Xiong Ru‐Qiao Jiang Qing‐Hui Lu Bi‐Sheng Yang Fa‐Yuan Li Guo‐An Tang 《Transactions in GIS》2019,23(2):259-274
Depression filling is a critical step in distributed hydrological modeling using digital elevation models (DEMs). The traditional Priority‐Flood (PF) approach is widely used due to its relatively high efficiency when dealing with a small‐sized DEM. However, it seems inadequate and inefficient when dealing with large high‐resolution DEMs. In this work, we examined the relationship between the PF algorithm calculation process and the topographical characteristics of depressions, and found significant redundant calculations in the local micro‐relief areas in the conventional PF algorithm. As such calculations require more time when dealing with large DEMs, we thus propose a new variant of the PF algorithm, wherein redundant points and calculations are recognized and eliminated based on the local micro‐relief water‐flow characteristics of the depression‐filling process. In addition, depressions and flatlands were optimally processed by a quick queue to improve the efficiency of the process. The proposed method was applied and validated in eight case areas using the Shuttle Radar Topography Mission digital elevation model (SRTM‐DEM) with 1 arc‐second resolution. These selected areas have different data sizes. A comparative analysis among the proposed method, the Wang and Liu‐based PF, the improved Barnes‐based PF, the improved Zhou‐based PF, and the Planchon and Darboux (P&D) algorithms was conducted to evaluate the accuracy and efficiency of the proposed algorithm. The results showed that the proposed algorithm is 43.2% (maximum) faster than Wang and Liu's variant of the PF method, with an average of 31.8%. In addition, the proposed algorithm achieved similar performance to the improved Zhou‐based PF algorithm, though our algorithm has the advantage of being simpler. The optimal strategies using the proposed algorithm can be employed in various landforms with high efficiency. The proposed method can also achieve good depression filling, even with large amounts of DEM data. 相似文献
8.
为查清山西省阳泉地区旅游地质资源分布状况,方便当地政府掌握区内旅游地质资源现状,为地质公园开发、保护与发展规划提供决策依据,山西省自然资源厅(原山西省国土资源厅)于2018年开展了“山西省阳泉地区旅游地质资源调查”项目,基于三维可视化遥感影像,采用目视解译方法,并结合已有地质资料和野外调查数据,获取了阳泉旅游地质资源分布信息。在阳泉中东部圈定了一条呈月牙形的旅游地质资源密集分布带,该分布带西起盂县藏山,向南东过平定玉皇洞,终至平定县娘子关,分布在碳酸盐岩区,集山地地貌景观、岩溶地貌景观和泉域地貌景观于一体,是我国北方地区规模较大、较为典型的碳酸盐岩地貌、岩溶地貌和泉域地貌出露区,在区域上连片分布,具有较高的开发潜力。建议在“藏山旅游区—岩溶地貌景区—娘子关旅游区”范围申请建立北方碳酸盐岩景观多成因类型地质公园。 相似文献
9.
Acta Geotechnica - In this study, the distinct element method (DEM) was employed to numerically explore the mechanical responses of granular soils and to extract key components for an elastoplastic... 相似文献
10.
因古隆起周缘页岩生烃时间晚、热演化程度低,目前已成为中扬子地区油气勘探的重要领域.雪峰古隆起形成于加里东末期,经历了后期复杂的沉积-构造演化,白垩系覆盖区勘探方向尚未明确.以雪峰古隆起西侧沅麻盆地北部为主要研究对象,通过对不整合于寒武系页岩之上的白垩系底部方解石脉与寒武系页岩方解石脉地球化学和包裹体对比分析,研究了古流体形成环境、来源及其对寒武系生烃演化过程的指示.研究结果表明:(1)白垩系脉体碳氧同位素与围岩具有相似性,REE无明显的Eu异常,与寒武系脉体Eu强正异常对比鲜明,表明白垩系脉体主要来自白垩系,受寒武系页岩的影响弱;(2)白垩系方解石脉采样位置位于构造高位,但是包裹体类型显示以纯水溶液包裹体为主,形成于弱还原-弱氧化的环境,未见沥青和明显的纯甲烷包裹体,表明寒武系大规模生排烃在白垩系沉积之前;(3)以包裹体均一温度和Ro为制约,结合区域地质特征恢复了沅麻盆地寒武系两种类型埋藏史,即沅麻盆地北部草堂凹陷早期深埋藏,白垩纪以来不具二次生烃的条件;辰溪凹陷南部早期浅埋藏,白垩系以来Ro可能由1.2%升至2.5%,二次生烃潜力较大,是下一步勘探的有利区. 相似文献